Abstract

Carbon dots (CDs)-based composites have shown impressive performance in fields of information encryption and sensing, however, a great challenge is to simultaneously implement multi-mode luminescence and room-temperature phosphorescence (RTP) detection in single system due to the formidable synthesis. Herein, a multifunctional composite of Eu&CDs@pRHO has been designed by co-assembly strategy and prepared via a facile calcination and impregnation treatment. Eu&CDs@pRHO exhibits intense fluorescence (FL) and RTP coming from two individual luminous centers, Eu3+ in the free pores and CDs in the interrupted structure of RHO zeolite. Unique four-mode color outputs including pink (Eu3+, ex.254 nm), light violet (CDs, ex.365 nm), blue (CDs, 254 nm off), and green (CDs, 365 nm off) could be realized, on the basis of it, a preliminary application of advanced information encoding has been demonstrated. Given the free pores of matrix and stable RTP in water of confined CDs, a visual RTP detection of Fe3+ ions is achieved with the detection limit as low as 9.8 μmol/L. This work has opened up a new perspective for the strategic amalgamation of luminous guests with porous zeolite to construct the advanced functional materials.

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