Abstract
A surprisingly simple and rapid methodology for large-area, lightweight, and thin laminate coatings with remarkable moisture barrier properties is introduced. Commercially available paperboards are coated with thin layers of nanocellulose. The nanocellulose coating induces a surface smoothening effect on the coated sheets as characterized by environmental scanning electron microscopy and white light interferometry. A moisture-protective layer of renewable alkyd resins is deposited on the nanocellulose precoated sheets using a water-borne dispersion coating process or lithographic printing. Through an auto-oxidation process, the applied alkyd resins are transformed into moisture sealant layers. The moisture barrier properties are characterized in detail by water vapor permeability measurements at different levels of relative humidity. The water vapor barrier properties of the nanocellulose precoated substrates were significantly improved by thin layers of renewable alkyd resins. The effect of the alkyd res...
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