Abstract

Abstract The synthesis, structural features and reactivity of the neutral phosphenium ion complexes (R)(R′)P[dbnd]MLn (MLn [dbnd] Co(CO)3, Mn(CO)4, MoCp(CO)2; R[dbnd] 2,4,6-tBu3C6H2O; R′ [dbnd] C[tbnd]CPh, CH[dbnd]CHPh, CH2C[tbnd]CH, CH[dbnd]C[dbnd]CH2) will be discussed.

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