Multifunctional magnetic Fe3O4/Cu2O-Ag nanocomposites with high sensitivity for SERS detection and efficient visible light-driven photocatalytic degradation of polycyclic aromatic hydrocarbons (PAHs)

Abstract

Polycyclic aromatic hydrocarbons (PAHs) with carcinogenic, teratogenic and mutagenic properties are persistent organic pollutants in the environment. Herein, the novel multifunctional Fe3O4/Cu2O-Ag nanocomposites (NCs) have been established for ultra-sensitive surface-enhanced Raman scattering (SERS) detection and visible light-driven photocatalytic degradation of PAHs. Fe3O4/Cu2O-Ag NCs with different amounts of Ag nanocrystals were synthesized, and the effect of Ag contents on SERS performance was studied by finite-difference time-domain (FDTD) algorithm. The synergistic interplay of electromagnetic and chemical enhancement was responsible for excellent SERS sensitivity of Fe3O4/Cu2O-Ag NCs. The limit of detection (LOD) of optimal SERS substrates (FCA-2 NCs) for Nap, BaP, Pyr and Ant was as low as 10-9, 10-9, 10-9 and 10-10 M, respectively. The SERS detection of PAHs in actual soil environment was also studied. Moreover, a simple SERS method was used to monitor the photocatalytic process of PAHs. The recovery and reuse of Fe3O4/Cu2O-Ag NCs were achieved through magnetic field, and the outstanding SERS and photocatalytic performance were still maintained even after eight cycles. This magnetic multifunctional NCs provide a unique idea for the integration of ultra-sensitive SERS detection and efficient photocatalytic degradation of PAHs, and thus will have more hopeful prospects in the field of environmental protection.