Abstract
Na+2Eu3+2:Ca6(PO4)6F2 is explored as a potential host for radioactive waste immobilization. Since Eu3+ ion is a surrogate of highly radioactive Am3+ ion, the photoluminescence (PL) characteristics of Eu3+ ion helped to investigate the possible distribution of hazardous and radioactive Am3+ ion among the two lattice sites in the matrix. It was observed that Am3+ will prefer to occupy the Ca2-site lattice which has a direct linkage to F atom. From DFT calculation we have found that both Eu3+ and Am3+ ions are following similar trend of distribution into the Ca2-site compared to Ca1-site which has no F atom linkage. The radiation stability of the compound was also investigated by PL study after irradiating it with a 60Co gamma source with different doses starting from 2 kGy to as high as 1000 kGy. It was observed that radiation induced changes were more surrounding the Ca1-site than in Ca2-site.Considering all the experimental and theoretical observations it is concluded that from radioactive waste immobilization point of view it is more preferable to dope the Am3+ ion into the Ca2 site. The Eu3+ doped compound was also found to be red color emitting phosphor materials with color purity of 95.24%.
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