Multi-fractal characteristics of pore structure for coal during the refined upgrading degassing temperatures

Abstract

The low-temperature nitrogen adsorption measurement is commonly used to describe the pore structure of porous medium, while the role of degassing temperature in the low-temperature nitrogen adsorption measurement does not attract enough attention, various degassing temperatures may lead to the different pore structure characterization for the same coal. In this study, the low-rank coal collected from Binchang mining area, southwest of Ordos Basin was launched the low-temperature nitrogen adsorption measurement under seven various degassing temperatures (120 °C, 150 °C, 180 °C, 210 °C, 240 °C, 270 °C and 300 °C), respectively, the dynamic change of the pore structure under refined upgrading degassing temperatures are studied, and it was also quantitative evaluated with the multi-fractal theory. The results show that the pore specific surface area and pore volume decrease linearly with the increased degassing temperatures, ranges from 12.53 to 2.16 m2/g and 0.01539 to 0.00535 cm3/g, respectively. While the average pore aperture features the contrary characteristics (various from 4.9151 to 9.9159 nm), indicating the pore structure has been changed during the refined upgrading degassing temperatures. With the upgrading degassing temperatures, the sizes of hysteresis loop decrease, and the connectivity of pore structure enhanced. The multi-fractal dimension and multi-fractal spectrum could better present the partial abnormal of pore structure during the refined upgrading degassing temperatures, and the quality index, Dq spectrum, D−10–D10 and multi-fractal spectrum could describe the homogeneity and connectivity of the pores finely. The degassing temperatures of 150 °C, 180 °C and 270 °C are selected as three knee points, which can reflect the partial abnormal of the pore structure during the refined upgrading degassing temperatures. Under the lower degassing temperature (< 150 °C), the homogeneity and connectivity of the pore feature a certain increase, following that it presents stable when the degassing temperatures various from 150 to 180 °C. The homogeneity and connectivity of the pore would further enhanced until the degassing temperature reaches to 270 °C. Because of the melting of the pore when the degassing temperature exceeds 270 °C, the complexity of pore structure increased. In this study, we advise the degassing temperature for low-temperature nitrogen adsorption measurement of low-rank coal should not exceed 120 °C.