Abstract

For many years, X-ray movies have been considered a promising tool for exploring and providing insights into chemical reactions. A simultaneous multi-element X-ray movie can further clarify the behavior difference of various elements and help investigate their interactions. The present short communication illustrates how to conduct multi-element X-ray movie imaging in a synchrotron facility solely by placing a micro-pinhole in front of a visible-light complementary metal-oxide semiconductor (CMOS) camera. It has been found that the CMOS camera can resolve X-ray fluorescence spectra when it is specially operated. In this work, a spatial resolution of ∼15 µm was achieved. In the X-ray movie, a movie frame acquisition time of 2 min and a spatial resolution of ∼50 µm were simultaneously achieved. It is clear that the CMOS camera can be a cost-efficient option for many researchers who wish to establish their own setup for visualizing chemical diffusion in various reactions.

Highlights

  • Movies are useful as a record of the overall progress of chemical reactions

  • The present short communication indicates the costefficient alternative of a visible-light complementary metaloxide semiconductor (CMOS) camera used for direct detection of X-rays (Janesick, 2001; Holst & Lomheim, 2007)

  • The visible-light CMOS camera (PCO.edge 5.5, PCO AG) used in the present work has 2560 Â 2160 pixels with a pixel

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Summary

Introduction

A movie captured in visible light cannot reveal the elemental composition of a reaction. X-ray fluorescence (XRF) can aid the identification of elements with quantitative information such as average concentration, and XRF imaging can reveal their spatial distribution. A movie comprising a continuous series of XRF images can be a powerful tool for exploring multi-element reactions such as ion exchange, composition segregation, selective precipitation and formation of chemicalgradient materials (Zhao & Sakurai, 2017a). It was found that the camera could resolve XRF spectra using laboratory X-ray sources (Zhao & Sakurai, 2017c). The camera operation is performed in a synchrotron facility and its multi-element movie imaging capability with potential for high spatial resolution is illustrated

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