Abstract
The diffusional behavior of selected hydrocarbons adsorbed in NaX zeolites were investigated with pulsed magnetic field gradient (PFG) NMR methods in two different ways. First, the exchange time τ exch of n-pentane between the interior and the exterior of the zeolite crystals was determined by two-dimensional diffusion exchange spectroscopy. The results were compared to the mean life time τ intra as obtained by fast NMR tracer desorption method. Second, the diffusion of a propylene–propane mixture adsorbed in the zeolite was studied by Fourier transform PFG NMR, thus employing the chemical shift of the individual organic constituents as a second dimension for a selective evaluation of the PFG NMR signal decays and the subsequent extraction of corresponding diffusion coefficients. Modifications of NMR pulse sequences necessary for the application of ultra-high pulsed magnetic field gradients of up to ± 35 T m - 1 in microporous materials are briefly discussed for both kind of experiments.
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