Abstract
A numerical algorithm for predicting the migration of multiple subsurface pollutants has been developed accounting for dispersion, convection, soluble complexation and solid phase accumulations (sorption). The basis of the model is a finite element solution of the mass transport equation. The essence of the algorithm is the treatment of the sorption terms as implicit functions of the total soluble concentrations facilitating a general and modularized treatment of solution phase and solid phase chemistry. Examples are presented illustrating the effects of soluble complexation and competitive sorption on the transport of multicomponent solutions.
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