Multicomponent oxide composites for carriers in catalytic applications

Abstract

AbstractBinary, ternary, and quaternary composite oxides of rare earths (La and Ce) with one or more of aluminum, magnesium, and zirconium, prepared by coprecipitation are studied. Potential use is carrier in steam or dry reforming of hydrocarbons and ethanol. Individual components influence specific surface area, porosity, acidity, hydrothermal stability, and oxygen storage capacity (OSC) differently. Interaction effects between components further influence these properties resulting in unexpected trends. Alumina and magnesia form solid solutions with zirconia until 650℃. Magnesia imparts better hydrothermal stability to zirconia. Aluminum and magnesium form MgAl2O4 spinel in ternary composites. Specific surface area varies linearly with alumina content. Alumina influences porosity, whereas magnesia influences pore diameter. The composites are mesoporous. Only binary composites present unimodal, pore size distribution. Composites containing alumina present type H2 isotherms while the remaining composites present H3 type isotherms. OSC increases over ZrO2/CeO2 5.7 to 15.3 molar. Magnesia and alumina affect microstructure and hydrothermal stability in contrasting ways. Thermogravimetry indicates that ternary composites of zirconia with alumina or magnesia form through oxolation. Surface hydroxyls with varying acidity are seen by FTIR in as synthesized samples. Magnesia and zirconia influence acidity in opposite ways, which impacts deactivation in the decomposition of 2‐methyl‐3‐butyn‐2‐ol.