Multi-ring Deposition Pattern of Drying Droplets.

Abstract

We propose a theory for the multi-ring pattern of the deposits that are formed when droplets of the suspension are dried on a substrate. Assuming a standard model for the stick-slip motion of the contact line, we show that as droplets evaporate many concentric rings of deposits are formed but are taken over by a solid-circle pattern in the final stage of drying. An analytical expression is given to indicate when the ring pattern changes to a solid-circle pattern during the evaporation process. The results are in qualitative agreement with existing experiments, and the other predictions on how the evaporation rate, droplet radius, and receding contact angle affect the pattern are all subject to an experimental test.