Abstract
AbstractThermally activated delayed fluorescence (TADF) is an emission mechanism whereby both singlet and triplet excitons can be harvested to produce light. Significant attention is devoted to developing TADF materials for organic light‐emitting diodes (OLEDs), while their use in other organic electronics applications such as sensors, has lagged. A family of TADF emitters, TPAPyAP, TPAPyBP, and TPAPyBPN containing a triphenylamine (TPA) donor and differing nitrogen‐containing heterocyclic pyrazine‐based acceptors is developed and systematically studied. Depending on the acceptor strength, these three compounds emit with photoluminescence maxima (λPL), of 516, 550, and 575 nm in toluene. Notably, all three compounds show a strong and selective spectral response to the presence of ZnCl2, making them the first optical TADF sensors for this analyte. It is demonstrated that these three emitters can be used in vacuum‐deposited OLEDs, which show moderate efficiencies. Of note, the device with TPAPyBPN in 2,8‐bis(diphenyl‐phoshporyl)‐dibenzo[b,d]thiophene (PPT) host emits at 657 nm and shows a maximum external quantum efficiency (EQEmax) of 12.5%. This electroluminescence is significantly red‐shifted yet shows comparable efficiency compared to a device fabricated in 4,4′‐bis(N‐carbazolyl)‐1,1′‐biphenyl (CBP) host (λEL = 596 nm, EQEmax = 13.6%).
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.