Abstract
Abstract The rigid and unique polyammonium binding site of fully protonated 5,15-bis(2-pyridyl)octaethylporphyrin allows novel discrimination of monoalkyl phosphate vs. dialkylphosphate as well as oxy- and dicarboxylic acids vs. monocarboxylic acid; the former are readily bound with the protonated porphyrin via multi-point interaction, while the latter not.
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