Multi-objective optimization of steam methane reformer in micro chemically recuperated gas turbine

Abstract

A kinetic theory, known as the Langmuir–Hinshelwood–Hougen–Watson adsorption model, is applied to describe the steam methane reforming (SMR) in a 500 kW scale micro chemically recuperated gas turbine (CRGT) cycle. The response surface models of important performance parameters, including the methane conversion, carbon monoxide selectivity, and chemically recuperated heat as a function of the temperature, pressure, steam-to-carbon ratio, and contact time are numerically obtained based on the cases selected by the central composite design. The factors affecting the SMR performance are analyzed, and the reformer performance is optimized using both the desirability function combined with the response surface methodology and the second generation non-dominated sorting genetic algorithm. Finally, performance of the optimized reformer and electrical efficiency of the micro CRGT cycle with the reformer are evaluated. Results reveal that the efficiency of the micro CRGT is 40.70%, which is much higher than the typical high-efficiency micro gas trubine without reformer.