Multi-heterostructured SnO2/SnSx embedded in carbon framework for high-performance sodium-ion storage.

Abstract

Heterostructure materials, as newborn electrode materials for rechargeable batteries, are attracting increasing attention due to their robust architectures and superior electrochemical performances. It is widely believed that the inner electric field induced at the interface can improve the electric conductivity and ion diffusion kinetics, thus enhancing the long-term stability and high-rate performance of the batteries. Although much progress is made on heterostructure construction, the performance of the batteries is still far from satisfying the commercial applications. In this work, a new type of SnO2/SnSx (x=1, 1.5) heterostructure embedded in carbon framework (C@SnO2/SnSx) is constructed via a facile sulfidation process. Compared to a single heterojunction, the multi-heterojunctions generated at SnO2/SnSx interface can induce an intensified built-in electric field, which promotes charge transportation and reaction kinetics of the electrode for Na-ions storage. Upon the sodiation process, the induced intensified electric field drives Na ions from Sn2S3 or SnO2 to SnS, while an inverse transportation of Na ions are accelerated upon the desodation process. As a result, C@SnO2/SnSx exhibits an outstanding reversible capacity of 510mAhg-1 after 300 cycles at 200mAg-1.