Multi-functional transparent electrode for reliable flexible perovskite solar cells

Abstract

Multilayer MoOx/Ag/MoOx (DMD) films are found to be transparent conducting electrodes for use in extremely stable and highly bendable flexible perovskite solar cells (PSCs). The optical transparency and electric properties of DMD and its role as a top electrode of PSCs were studied by changing the thickness of the MoOx layer. Although the MoOx thickness was shown to have a negligible effect on the sheet resistance of DMD, the transmittance of visible light, selective carrier transport capability, and long-term stability of a device considerably depend on this factor. The sandwich structure of a 20-nm-thick MoOx, 7-nm-thick Ag, and 20-nm-thick MoOx exhibits a high transmittance and large photon–electron conversion rate of PSCs. In addition, PSCs using the DMD top electrode maintain 92% of their initial current density after 24 h of continuous operation owing to a UV light cut-off of the top illumination. Moreover, the overall structure of DMD blocks the diffusion of water and oxygen molecules from real environmental conditions. At the same time, the underlying/upper MoOx layer retards the degradation through a chemical reaction between Ag and the halide ions inside the cells, as well as foreign ions from outside the polluted atmosphere. When DMD is applied to flexible PSCs on Ti foil, the PCE reaches 14.5%, and mechanical integrity of the PSCs is maintained at a bending radius of 4 mm.