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Abstract
The design and preparation of homochiral metal–organic coordination polymers is presently a topic of intense focus. Herein, we present a series of isomorphous Ln(III)–camphorate compounds with the P65 chiral space group. The overall structural feature is the hex rod-packing architecture, where each helical {Ln–O}n inorganic substructure connects to six analogs via chiral D-cam spacers (D-H2Cam = D-camphoric acid). Moreover, the Ln-related magnetic, fluorescent and chirality-related ferroelectric merits of these compounds are explored.
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