Abstract
Blue thermally activated delayed fluorescence (TADF) dyes are basically combinations of strong acceptors and weak donors. In this work, a weak acceptor P═O group was employed to construct a series of weak acceptor–strong donor (WASD)-type emitters with a phenoxazine donor, namely 10-(4-(diphenylphosphoryl)phenyl)-10H-phenoxazine (SPXZPO), 10,10′-(4,4′-(phenylphosphoryl)bis(4,1-phenylene))bis(10H-phenoxazine) (DPXZPO), and 10,10′,10″-(4,4′,4″-phosphoryltris(benzene-4,1-diyl))tris(10H-phenoxazine) (TPXZPO). Owing to the insulating effect of P═O on conjugation extension and intramolecular electronic communications, the photoluminescence spectra of these molecules are almost identical, manifesting the superiority of WASD structure in emission color preservation. Simultaneously, the multi-dipolar characteristics of TPXZPO enhance the intramolecular charge transfer (ICT), facilitating reverse intersystem crossing for higher TADF efficiency and shorter lifetime. As a consequence, TPXZPO realized the desired pure...
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