Multi-component trace analysis of organic xenobiotics in surface water containing suspended particular matter by solid phase extraction/gas chromatography–mass spectrometry

Abstract

Suspended particulate matter (SPM) often disturbs the analysis of surface water by conventional methods, such as liquid–liquid extraction (LLE) or solid phase extraction (SPE), caused by insufficient extraction or by plugging. Water and SPM are therefore often separately analysed, which is associated with high expenditure of time, work and costs. Hence, SPM is partly ignored, if the fraction of sorptively bound analytes is small compared to the total analyte concentration. However, the European Water Framework Directive (WFD, Directive 2000/60/EC) requires explicitly an investigation of the whole water sample including SPM, because many priority and priority hazardous substances can sorb substantially to SPM. Therefore, an SPE disk based method was developed for the determination of 54 priority and priority hazardous pollutants including polycyclic aromatic hydrocarbons (PAH), polychlorinated biphenyls (PCB), polybrominated diphenyl ethers (PBDE), organic chlorinated pesticides (OCP) and other pesticides in surface water containing SPM. The developed SPE disk method allows analysis of 1L surface water containing up to 1000mg SPM without prior separation of SPM in about 2h including gas chromatography–mass (GC–MS) spectrometry analysis. The limits of quantification vary in a range of 0.8 to 38ng/L.