Mullite ceramic foams with tunable pores from dual-phase sol nanoparticle-stabilized foams

Abstract

Particle-stabilized foams employing dual-phase sol of boehmite in combination with silica to prepare mullite ceramic foams has been proposed for the first time. The obtained mullite ceramic foams possess hierarchical pores, that is micropores derived from the air bubble templates and open windows formed by grain growth at thin area of pore wall according to the mullitization reaction. Furthermore, nanoparticles favor the improvement of specific surface area of ceramic foams, and wrinkles caused by drying shrinkage would retain when sintering at low temperature of 900℃-1100℃, leading to high specific surface area of 94.4-219.2 m2/g. The achieved mullite ceramic foams present relatively high compressive strength of 6.6−40.4 MPa at a high open porosity of 64.0 %–87.0 %, and their thermal conductivity could reach as low as 0.10 W/(m·K), which would make them promising lightweight materials applied in broad fields including thermal insulations, filters, bio-scaffolds, catalyst supports and the like.