MSW Compost Valorization by Pyrolysis: Influence of Composting Process Parameters.

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The valorization of urban solid waste compost (MSW) in two different composting conditions (different aeration and humidity) has been studied (we work with the hypothesis that the composting process can have a significant influence on a subsequent pyrolysis process). The influence of composting on subsequent pyrolysis of the material was assessed by examining the kinetics of the process, maximizing hydrogen production and minimizing the activation energy. The thermogravimetric analysis carried out on the samples have shown that they have a greater loss of weight of 9–14% at 270–275 °C and 22–27% at 444–446 °C. Using the Kissinger–Akahira–Sunose method, the activation energy values are found to be in the range of 57.78–581.69 kJ mol–1, and the assumption that pyrolysis of compost could be modeled by a first-order reaction may be a suitable approximation. The analysis of the gases produced from the pyrolysis process revealed that hydrogen increases in concentration as composting time advances until intermediate time. In this form, the composting process could be a suitable previous treatment for improving the pyrolysis process. In fact, decreasing aeration and moisture in the MSW composting process led to the production of an increased amount of hydrogen (8.3%) by pyrolysis of the resulting compost and also to a decreased activation energy (102.8 kJ mol–1). These effects were also observed before the end of the composting process in the form of maximum hydrogen production and minimum activation energy after 20 days.