Abstract
Ni x (Cu 0.5Fe 0.5) 1− x Cr 2S 4 has been studied by Mössbauer spectroscopy and X-ray diffraction. The crystal is found to have a cubic spinel structure and the lattice constant decreases with increasing Ni concentration. The iron ions are in ferric states and occupy the tetrahedral sites. When the nickel concentration at the tetrahedral sites increases from 10 to 30%, magnetic hyperfine field and Néel temperature are found to decrease by 2 and 9%, respectively. As the interatomic distance decreases by 0.4%, Debye temperature increases rapidly by 37%.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
