Abstract
The effect of pigments on the development of corrosion products between the painting system and metal surface when exposed to marine environments has been discussed. The pigments studied were; Red Mud Zinc chromate, Zinc chromate, Red oxide Zinc Phosphate, Manganese Phosphate Barium chromate and Basic Lead Silico Chromate. Mossbauer Spectroscopy revealed that the upper rust layer in all the cases consisted ofγ-Fe203,γ-FeOOH andα-FeOOH. The lower rust layer immediately in contact with the metal surface consisted of an asymmetrical doublet due to γ-FeOOH.
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