Abstract
The acyl derivatives of 3,3′,4,4′-tetramethyldi- phosphaferrocene (TMDPF) have been examined in strong acids by 57Fe Mössbauer, 1H and 31P NMR spectroscopy. As with ferrocenyl ketones, protonation was found to occur at the keto function, the diphosphaferrocenyl ketones having comparable or, in some cases, reduced basicities compared to ferrocenyl ketones. [p ]Trends in the 57Fe Mössbauer parameters are not as additive as in ferrocene systems due to steric crowding. The keto derivatives show some unusual deuteriation patterns and these have been compared with those of ferrocenyl ketones. The 13C spectra of several derivatives have been reported to illustrate the rather complex stereochemistry found in these derivatives.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
