Morse potential in relativistic contexts from generalized momentum operator: Schottky anomalies, Pekeris approximation and mapping

Abstract

In this work, we explore a generalization of the Dirac and Klein–Gordon (KG) oscillators, provided with a deformed linear momentum inspired in nonextensive statistics, that gives place to the Morse potential in relativistic contexts by first principles. In the (1 + 1)-dimensional case, the relativistic oscillators are mapped into the quantum Morse potential. Using the Pekeris approximation, in the (3 + 1)-dimensional case, we study the thermodynamics of the S-waves states (l = 0) of the H2, LiH, HCl and CO molecules (in the non-relativistic limit) and of a relativistic electron, where Schottky anomalies (due to the finiteness of the Morse spectrum) and spin contributions to the heat capacity are reported. By revisiting a generalized Pekeris approximation, we provide a mapping from (3 + 1)-dimensional Dirac and KG equations with a spherical potential to an associated one-dimensional Schrödinger-like equation, and we obtain the family of potentials for which this mapping corresponds to a Schrödinger equation with non-minimal coupling.