Morphology and mechanical properties of direct injection molded polypropylene/thermotropic copolyester blends

Abstract

AbstractBlends of two grades of polypropylene (PP) with thermotropic copolyester (Rodrun) contents of up to 40% were obtained by direct injection molding at different processing temperatures. In the skin of the molded specimens rather long fibers were seen in blends with low‐viscosity PP, whereas sheets were found when the high‐viscosity PP was the matrix. In the core, the viscosity of the matrix played a more relevant role than the viscosity ratio on the orientation level of the dispersed Rodrun phase. The better mechanical properties of the blends with the low viscosity PP are attributed to the morphology change of the dispersed phase from sheets to fibers when the viscosity of the matrix decreased.