Morphology and characteristics of laser-induced aluminum plasma in argon and in air: A comparative study

Abstract

In laser-induced breakdown spectroscopy (LIBS), ablation takes place in general in an ambient gas of the atmospheric pressure, often in air but also in noble gas such as argon or helium. The use of noble gas is known to significantly improve the performance of the technique. We investigate in this work the morphology and the characteristics of induced plasma in argon and in air. The purpose is to understand the mechanism of the analytical performance improvement by the use of argon ambient with respective to air ambient and the dependence on the other experimental parameters such as the laser fluence. The observation of plasma morphology in different ambient gases provides also information for better design of the detection system which optimizes the signal collection according to the used ambient gases. More specifically, the expansion of the plasma induced on an aluminum target with nanosecond infrared (1064nm) laser pulse in two ambient gases, argon and the atmospheric air, has been studied with spectroscopic imaging at short delays and with emission spectroscopy at longer delays. With relatively low ablation laser fluence (65J/cm2), similar morphologies have been observed in argon and in air over the early stage of plasma expansion, while diagnostics at longer delay shows stronger emission, higher electron density and temperature for plasma induced in argon. With higher ablation laser fluence (160J/cm2) however, different expansion behaviors have been observed, with a stagnating aluminum vapor near the target surface in air while a propagating plume away from the target in argon. The craters left on the target surface show as well corresponding difference: in air, the crater is very shallow with a target surface chaotically affected by the laser pulse, indicating an effective re-deposition of the ablated material back to the crater; while in Ar a deeper crater is observed, indicating an efficient mass removal by laser ablation. At longer delays, a brighter, denser and hotter plasma is always observed in argon than in air as with lower ablation laser fluences. The observed different influences of the ambient gas on the plasma expansion behavior for different laser fluences are related to the different modes of laser-supported absorption waves, namely laser-supported combustion (LSC) wave and laser-supported detonation (LSD) wave.