Abstract
The reduction reaction of NO by CO over Pd is studied by means of a Monte Carlo simulation. A reaction mechanism similar to that established previously in the literature for Rh and a set of recently published kinetics parameters for Pd determined from experimental work are assumed. The heterogeneous effects of the catalytic substrate are analyzed by simulating various surfaces: a uniform square and hexagonal lattice, the incipient percolation cluster (IPC) fractal, and a lattice formed by a cluster distribution supported on a deterministic fractal. The results interpret reasonably the experimental data published recently in the case of crystals and supported catalysts.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
