Abstract
Monte Carlo (MC) simulation data for additive binary hard sphere mixtures are reported for dilute concentrations of the large sphere. Using a single occupancy linked cell method, binary hard sphere solutions with a size ratio of 5 are simulated at high reduced density and low concentration of the large sphere. Data for the solute-solvent pair distribution function show that at the lowest concentrations of the large sphere simulated, the Boublik-Mansoori-Carnahan-Starling-Leland (BMCSL) equation underestimates the contact value; whereas the recently proposed Henderson-Chan (HC) equation gives a good prediction. For the solute-solute contact value at the colloidal limit, the MC data lie between the two predictions. The BMCSL equation underestimates, while the HC equation overestimates, the correct solute-solute contact value.
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