Abstract
Via self-assembly of the molecular precursors sodium orthovanadate and isopropyltin-dihydroxide-chloride the unprecedented organic–inorganic hybrid polyoxoanion [( i PrSn) 3(OV) 4O 10(OH) 3] 2− was synthesized in dimethylsulfoxide (DMSO) and isolated as its sodium salt Na 2[( i PrSn) 3(OV) 4O 10(OH) 3]·5H 2O·3DMSO. This spherical nanosized anion is composed of two different structural subunits, a well-known trinuclear monoorganotin-polyoxo-hydroxo unit with octahedrally coordinated tin atoms and a new open-chain, branched isopolyoxo tetravanadate(V) with tetrahedrally coordinated vanadium atoms.
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