Abstract

The reaction of terpyridine derivatives L1/L2 with Ln(NO3)3 led to the formation of three new mononuclear complexes with formulae [LnL1(CH3OH)(H2O)(NO3)2]NO3•2CH3OH (Ln=Yb, 1 ; Ln=Dy, 2 ) and [DyL2(NO3)3(H2O)]•2CH3OH ( 3 ). Complexes 1 , 2 and 3 were characterized by crystal structure determination, magnetic properties study. Ac magnetic susceptibility measurements reveal that all complexes exhibited field-induced single-ion magnet (SIM) behavior.

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