Abstract
AbstractFour mononuclear complexes were synthesized through simple self‐assembly reactions, [Dy(L1)2(NO3)H2O] (1), [Tb(L1)2(NO3)MeOH] (2), [Ho(L1)2(NO3)H2O] ⋅ 5.5H2O (3) (HL1=4‐bromo‐2‐((quinolin‐8‐ylimino)methyl)phenol), and [Dy(L2)2(NO3)H2O] (4) (HL2=2,4‐dibromo‐6‐((quinolin‐8‐ylimino)methyl)phenol). They are characterized by their structures and magnetic properties. The magnetic data show that the Dy clusters all have obvious frequency‐dependent magnetic behavior and slow magnetic relaxation effects. The complex 1 under an external dc field with the anisotropic barrier of 14.41 K and pre‐exponential factor τ0=2.70×10−6 s, the complex 4 under an external dc field with the anisotropic barrier of 64.36 K and pre‐exponential factor τ0=2.38×10−7 s.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Zeitschrift für anorganische und allgemeine Chemie
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
