Abstract
Six new Ln(III) complexes viz., [Gd(tptz)(SCN)3(CH3OH)2OH2]·CH3OH (1), [Eu(tptz)(SCN)3(CH3OH)2OH2]·CH3OH (2), [Tb(tptz)(SCN)3(OH2)3]4 (3), [Gd(tptz)(OBz)2(μ-OBz)OH2]2·2H2O (4), [OH2(OBz)2(tptz)Eu1(μ-OBz)2Eu2(tptz)(OBz)2OH2]·CH3OH·7H2O (5), and {[Tb1(tptz)(OBz)2(μ-OBz)]2·[Tb2(tptz)(OBz)3CH3OH]2}·2CH3OH·4H2O (6) (Ln = Gd, Eu, Tb; tptz = 2,4,6-tris(2-pyridyl)-1,3,5-triazine; BzONa = sodium benzoate), have been synthesized and characterized by physicochemical methods including single-crystal X-ray crystallography. The X-ray studies demonstrate that 1–3 are mononuclear, whereas 4–6 are binuclear. The photophysical properties of 1–6 have been studied with ultraviolet absorption and emission spectral studies. Their thermal properties have been studied by thermogravimetric (TG) and derivative thermogravimetric analysis (DTG), demonstrating that the final product after decomposition was Ln2O3 for all these complexes.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
