Abstract
AbstractThe 2‐ethoxycarbonylallyl 5‐(1,2‐dithiolane‐3‐yl)‐pentanoate monomer (AODS) includes in its molecular structure CC and SS reactive bonds allowing it to behave as a bi‐functional monomer, possessing two groups, however, with different reactivity for use in polymer chain building. The polymerization‐specific features of this monomer are the absence of auto‐acceleration and polymer chain crosslinking. Polymerization proceeds readily through most free‐radical initiators. One exception, carboxy‐peroxides are rapidly decomposed without the production of free radicals. AODS is partially converted to a gel without the consumption of double bonds during monomer dissolution in certain organic solvents and after being mixed in solution with carboxy‐peroxides. The determined AODS‐co‐MMA copolymerization parameters are r1 = 2.61, r2 = 0.23 if Luperco peroxide is used as a polymerization initiator, and r1 = 2.71, r2 = 0.38 if AIBN is used. magnified image
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