Abstract
AbstractThe thermal treatment of CuCl2 with N‐(4′‐vinylbenzyl)cinchonidinium chloride (L1) afforded a monomeric discrete homochiral copper(II) complex N‐4′‐(vinylbenzyl)cinchonidinium trichlorocoprate(II) (1). Their applications to the enantioselectively catalytic alkylation reaction of N‐(diphenylmethylidene)glycine tert‐butyl ester (3) show that the higher ee value observed in catalyst 1 than that in the corresponding free ligand L1 is probably due to the rigidity enhancement after the coordination of N atom of quinoline ring to the copper ion.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
