Abstract
The photodimerization of trans-p-bromocinnamic acid, possessing a stack crystal structure in which each monomer has two monomeric nearest neighbors in the stack dimension, by monitored by FTIR spectroscopy. Upon UV irradiation, UV spectral FTIR and transient absorptions indicated that residual monomers were present in altered crystal-structure environments. The results are interpreted according to a kinetic model in which monomers have one or two dimeric nearest neghbors at intermediate levels of photoconversion
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