Abstract

HighlightsMonodomain liquid crystals of graphene oxide over 30 cm is realized by boundary-free sheargraphy.The achieved monodomain liquid crystals have bidirectional sheet ordering, exhibiting unique optical, rheological, and conductive properties.Boundary-free sheargraphy extends to freely design delicate topology of two-dimensional colloids, including topological structures with defect strength from − 2 to + 2 and complex polydomain.

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