Monodisperse nanospheres of yttrium oxysulfide: Synthesis, characterization, and luminescent properties

Abstract

A red long-lasting phosphorescent material, monodisperse Y 2O 2S: Eu 3+, Mg 2+, Ti 4+ nanospheres have been prepared successfully. Y(OH)(CO 3): Eu 3+ nanospheres were firstly synthesized via an urea-based homogeneous precipitation technique to serve as the precursor. Nanospheres long-lasting phosphors Y 2O 2S: Eu 3+, Mg 2+, Ti 4+ were obtained by calcinating the precursor in CS 2 atmosphere. XRD investigation shows a pure phase of Y 2O 2S, indicating no other impurity phase appeared. SEM observation reveals that the structures are nanosphere. The Y 2O 2S: Eu 3+, Mg 2+, Ti 4+ nanospheres with particle size about 100–150 nm show uniform size and well-dispersed distribution. After irradiation by ultraviolet radiation with 325 nm for 5 min, the phosphor emitted red color long-lasting phosphorescence corresponding to typical emission of Eu 3+ ion. The main emission peaks are ascribed to Eu 3+ ions transition from 5D J ( J = 0, 1, 2) to 7F J ( J = 0, 1, 2, 3, 4). Both the PL spectra and luminance decay revealed that this phosphor had efficient luminescent and long-lasting properties. It was considered that the red-emitting long-lasting phosphorescence was due to the persistent energy transfer from the traps to the Ti 4+ and Mg 2+ ions.