Abstract
Digestive ripening (DR) is a postsynthetic protocol for the transformation of a colloid consisting of polydisperse metal nanoparticles (NPs) into a colloid composed of nearly monodisperse metal nanoparticles. This process is brought about by the digestive ripening agent, typically an organic ligand with a long alkyl chain at one end and a functional group at the other, at the boiling point of the solvent in which it is carried out, requiring long periods of time. In this work, digestive ripening of polydisperse Ag and Au nanoparticles brought about by ionic liquids (ILs) under very mild conditions (∼273 K, ∼30 min) to obtain nearly monodisperse nanoparticles has been demonstrated. Herein, the ionic liquid plays a dual role, as a digestive ripening and a stabilizing agent for the nanoparticles. Ionic liquid-assisted digestive ripening under such mild temperatures and short period of time has hitherto not been reported.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Langmuir : the ACS journal of surfaces and colloids
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.