Abstract

AbstractYttrium dialkyl complexes were prepared for three different 2,6‐diisopropylphenyl‐substituted benzamidinate ligands. The electron‐donating ability of the parent ligand (L1) was decreased by a pentafluorophenyl backbone substituent (L2), and enhanced by addition of a pendant Lewis base (L3). The corresponding cationic monoalkyl species were generated and compared in catalytic ethene polymerization.

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