Abstract
Rhodium(I) and iridium(I) mixed complexes of the formulae [M(diolefin)LL′]ClO4, [M(diolefin)L2L′]ClO4, [(diolefin)L′Ir(μ-L)2IrL′(diolefin)](ClO4)2, [(diolefin)L′M(μ-L-L)ML'(diolefin)](ClO4)2, [(diolefin)Rh{μ-(L-L)}2Rh(PPh3)2](ClO4)2 and [(diolefin)L′Ir{μ-(L-L)}2IrL′ (diolefin)](C1O4)2, (L=monodentate sulphur ligand, L-L=bidentate sulphur ligand, L′=group Vb ligand; M=Rh, diolefin=1,5-cyclooctadiene (COD) or 2,5-norbornadiene (NBD); M=Ir, diolefin=COD) are described.
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