Monitoring the efficiency of electro-kinetic soil remediation process with geophysical surveying method

Abstract

Geoelectric surveying is a useful method of non-invasive investigation (e.g.: for the purpose of space delineation or time dependant monitoring) of subsurface contaminants. The measured onsite electrical resistivity values are a function of certain soil parameters and the electric properties of the contaminant. With executing time domain field surveys before and after the remediation process its efficiency on contamination removal can be valorized.In this study we present a field case to illustrate the applicability of the geoelectric method for monitoring the efficiency of hydrocarbon removal and highlighting the problems of interpretation due to change of soil parameters and various hydrocarbon composition. Due to the side effects of electro-kinetic soil remediation process some soil parameters affecting the electrical resistivity are also changed. Therefore, when interpreting the data the of field survey one must be able to separate the geoelectric response of the remnant contamination from the changed soil parameters. The paper presents a multilevel interpretation method when the measured electrical resistivity data were correlated with the time-domain results of detailed soil sample analytics including particle size distribution, physical properties, and chemical composition. As a result we were able to separate the time domain geoelectric effects of the soil from the geoelectric response of the hydrocarbon contamination and we could correlate the electrical resistivity anomalies with the integrated effects of hydrocarbon content and changes in the soil due to the remediation treatment.