Abstract
The goal of this work is to study the alternative practices for monitoring the salinity of water using a combination of portable vis-NIR spectrometer and machine learning approachs. Along 80 km of the Tha Chin River basin from the Gulf of Thailand, the data of salinity and NIR spectrum were collected during winter and summer seasons of Thailand. Salinity of water samples was measured by using a handheld electrical conductivity meter and NIR spectra was recorded with portable FQA-NIR GUN in the wavelength range of 600 to 1100 nm. The 10 machine learning models including partial least square regression (PLS), support vector machine (SVR), decision tree (DT), random forest (RF), adaptive boosting (AB), gradient boosting (GB), bagging meta-estimator (BME), extremely randomized trees (ERT), backpropagation neural networks (BPNN) and hybrid principal component analysis-neural network (PCNN) were applied to train the NIRs models for predicting salinity. All machine learning algorithms showed good prediction results which Rp2 values were higher than 0.84. The models built by tree-based algorithms (DT, RF, AB, GB, BME and ERT) displayed higher performances of calibration set and prediction set than those of PLS, SVM, BPNN and PCNN. Among these, the ERT algorithm showed the best performance Rp2 of 0.97, RMSEP of 0.41 g/L and RPD of 6.00. It was shown that NIR spectroscopy coupled with machine learning could be an alternative simpler way for predicting salinity of water.
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