Monitoring of pesticide residues in peppers from Çanakkale (Turkey) public market using QuEChERS method and LC-MS/MS and GC-MS/MS detection.

Abstract

Residue analyses were conducted for 283 pesticide active ingredients on pepper samples collected from the local markets (between April and November) of Çanakkale province of Turkey by using QuEChERS method and LC-MS/MS and GC-MS/MS devices. In present pepper samples, 35 different pesticide residues were detected. About 25.0% (27 samples) of present samples had single residue and 43.5% (47 samples) had multiple residues. Of the detected pesticides, acetamiprid, triadimenol, imidacloprid, boscalid, pirimiphos-methyl, tebuconazole, and metalaxyl were the most common ones, while carbendazim/benomyl, fenpropathrin, and thiram were the banned ones. Moreover, 24 of the pesticide residues detected were above the MRL values, 19 pesticides were in the "moderately hazardous (II)," and two pesticides were in the "extremely hazardous (Ib)" class (WHO). Present findings revealed that consumer health may be in danger despite all legal measures by the Ministry of Agriculture and Forestry of Turkey, thus greater emphasis should be put on monitoring of pesticide use and residues.