Monitoring of CO2 and CO2 oil-based foam flooding processes in fractured low-permeability cores using nuclear magnetic resonance (NMR)

Abstract

CO2 flooding is an important method in CO2 enhanced oil recovery (EOR) but is usually accompanied by a low efficiency for the fractured low-permeability formation due to CO2 low viscosity and high mobility. In this paper, a comprehensive experimental research effort including flooding and NMR testing is conducted to investigate the oil recovery and mobility control effects of a novel CO2 oil-based foam in fractured low-permeability cores. First, the foaming performance of the compound surfactant SF in crude oil that consists of Span20 and fluorochemical surfactant F-1 is evaluated by the blender stirring method. The surfactant SF exhibits a good foaming performance in crude oil with a foam volume of 290 mL and a half-life of 352 s. The bubble film is notably thickened, which results in a stable oil-based foam. Second, CO2 flooding and CO2 oil-based foam flooding in nonfractured and fractured cores are conducted under reservoir conditions. CO2 oil-based foam flooding can significantly improve the oil recovery and increase the sweep volume of injected CO2. Consequently, the oil recovery in fractured cores increases by 47.8%, and that in nonfractured cores increases by 39.1%. Third, the residual oil saturation in the cores is tested by NMR. The residual oil saturation of fractured and nonfractured cores after CO2 oil-based foam flooding is low and distributed evenly, indicating that CO2 oil-based foam reduces CO2 mobility and yields a relatively uniform displacement throughout the core.