Momentum microscopy of Pb-intercalated graphene on SiC: Charge neutrality and electronic structure of interfacial Pb

Abstract

Intercalation is an established technique for tailoring the electronic structure of epitaxial graphene. Moreover, it enables the synthesis of otherwise unstable two-dimensional (2D) layers of elements with unique physical properties compared to their bulk versions due to interfacial quantum confinement. In this work, we present uniformly Pb-intercalated quasi-freestanding monolayer graphene on SiC, which turns out to be essentially charge neutral with an unprecedented $p$-type carrier density of only $(5.5\pm2.5)\times10^9$ cm$^{-2}$. Probing the low-energy electronic structure throughout the entire first surface Brillouin zone by means of momentum microscopy, we clearly discern additional bands related to metallic 2D-Pb at the interface. Low-energy electron diffraction further reveals a $10\times10$ Moir\'e superperiodicity relative to graphene, counterparts of which cannot be directly identified in the available band structure data. Our experiments demonstrate 2D interlayer confinement and associated band structure formation of a heavy-element superconductor, paving the way towards strong spin-orbit coupling effects or even 2D superconductivity at the graphene/SiC interface.