Momentum mapping spectrometer for probing the fragmentation dynamics of molecules induced by keV electrons

Abstract

We describe a new experimental setup for studying the fragmentation dynamics of molecules induced by the impact of keV electrons using the well-known technique of recoil ion momentum spectroscopy. The apparatus consists of mainly a time- and position-sensitive multi-hit particle detector for ion analysis and a channel electron multiplier detector for detecting the ejected electrons. Different components of the setup and the relevant electronics for data acquisition are described in detail with their working principles. In order to verify the reliable performance of the setup, we have recorded the collision-induced ionic spectra of the CO2 molecule by the impact of keV electrons. Information about the ion pairs of CO+:O+, C+:O+ and O+:O+ resulting from dissociative ionizing collisions of 20 and 26 keV electrons with a dilute gaseous target of CO2 molecules has been obtained. Under conditions of the present experiment, the momentum resolutions of the spectrometer for the combined momenta of CO+ and O+ ions in the direction of the time-of-flight axis and perpendicular to the direction of an electron beam are found to be 10.0 ± 0.2 and 15.0 ± 0.3 au, respectively.