Abstract
Momentum distributions are calculated for electrons in the C–C and C–H bonds in hydrocarbons, using analytic SCF functions for atomic carbon orbitals and Heitler–London-type functions for the two paired electrons in the C–C and C–H bonds. The positron wave function is assumed to be a constant. The computed momentum distributions are then compared with high-precision experimental distributions obtained from positron-annihilation angular correlation experiments.
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