Molybdenum induced defective WO3 multifunctional nanostructure as an electrochromic energy storage device: Novel assembled photovoltaic-electrochromic Mo–WO3 film

Abstract

In this work, a self-powered electrochromic device incorporating molybdenum-doped tungsten oxide (WO3) is developed for enhanced performances, offering a potential solution for energy efficient technologies. Defective nanostructure of WO3, enabled with molybdenum doping, is achieved through an electrochemical co-deposition method. A film of Mo–WO3 is investigated for multifunctional purposes, acting as both an electrochromic (EC) and energy storage device (ESD). As an EC film, it exhibits an optimal optical contrast of 84.5 %, minimum coloration time of 0.4 s, high coloration efficiency of 90.4 cm2/C, and excellent optical stability. In ESD applications, Mo–WO3 displays charge-transfer resistance of 7.6 Ω, a commendable capacitance of 39.1 mF/cm2, and excellent capacitance retention of 80.4 %. The integration of Mo ions into the WO3 nanostructure results in the formation of oxygen defect sites, which enhances the mobility of Li+ ions over the amorphous and deagglomerated morphology of Mo–WO3. Furthermore, the EC activity of Mo–WO3 film does not require an external power source as the film is powered by an integrated quantum dot-sensitized solar cell (QDSSCs). The open circuit voltage of 0.62 V, resulting from the QDSSCs power source, successfully facilitates the switching operation of the Mo–WO3 EC film.