Abstract
Dioxomolybdenum(VI) complexes including MoO2(dipic)(HMPA)2a and MoO2(dedtc)22b(dipic = 2,6-pyridinedicarboxylate; HMPA = hexamethylphosphoramide; dedtc =N,N-diethyl dithiocarbamate) catalyse the allylic amination of alkenes by phenyl hydroxylamine; the reactions are characterized by a high degree of regioselectivity resulting from double bond migration.
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